Efficient capture of Cr(VI) by carbon hollow fibers with window-like structure.

Abstract

Removal of toxic Cr(VI) from contaminated water is significant for environmental protection. High efficient adsorbents with outstanding adsorption performance are highly demanded. Herein, we reported that window-like structured carbon hollow fibers (WL-CHF) derived from Enteromorpha prolifera could capture toxic Cr(VI) from aqueous solutions with high adsorption capacity, fast adsorption rate, and excellent recyclable performance. The excellent adsorption performance could be attributed to the unique structure that combines a variety of advantages: large specific surface area, fast diffusion processes, and easy access of adsorption sites for Cr(VI). In addition, the adsorption process was fitted well with pseudo-second-order model and Langmuir isotherm model. The potential mechanism on Cr(VI) removal includes reduction-cation exchange and electrostatic interaction with surface oxygen-containing functional groups. This study highlights new opportunities for designing adsorbents for Cr(VI) removal from Cr-polluted water.