Abstract

Highly bright and efficient blue organic light-emitting devices based on two oligo(phenylenevinylene) derivatives, 1,4-di(4′-N,N-diphenylaminostyryl)benzene (DPA-DSB) and 2,5,2′,5′-tetrastyryl-biphenyl (TSB), are fabricated. Using poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid) combined with 4,4′,4″-tri(N-carbazolyl) triphenylamine as the hole-transporting layer and DPA-DSB doped TSB as the blue emitter, a maximum luminous efficiency of 12.2 cd/A (corresponding to an external quantum efficiency of 6.2%) and a maximum power efficiency of 6.39lm∕W are obtained. The maximum brightness of 17350cd∕m2 is attained. These fairly high brightness and efficiencies are due to the efficient energy transfer from TSB to DPA-DSB and depression of concentration quenching by doping.

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