Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP2O7:Cr3+ Phosphor for Nondestructive Examination.

Abstract

Broad-band near-infrared (NIR) phosphors are essential to assembling portable NIR light sources for applications in spectroscopy technology. However, developing inexpensive, efficient, and thermally stable broad-band NIR phosphors remains a significant challenge. In this work, a phosphate, KAlP2O7, with a wide band gap and suitable electronic environment for Cr3+ equivalent substitution was selected as the host material. The synthesized KAlP2O7:Cr3+ material exhibits a broad-band emission covering 650-1100 nm with a peak centered at 790 nm and a full width at half-maximum (fwhm) of 120 nm under 450 nm excitation. The internal quantum efficiency (IQE) was determined to be 78.9%, and the emission intensity at 423 K still maintains 77% of that at room temperature, implying the high efficiency and excellent thermal stability of this material. Finally, a NIR phosphor-converted light-emitting diode (pc-LED) device was fabricated by using the as-prepared material combined with a 450 nm blue LED chip, which presents a high NIR output power of 32.1 mW and excellent photoelectric conversion efficiency of 11.4% under a drive current of 100 mA. Thus, this work not only provides an inexpensive broad-band NIR material with high performance for applications in NIR pc-LEDs but also highlights some strategies to explore this class of materials.