Efficient and Stable All-Inorganic Niobium-Incorporated CsPbI2Br-Based Perovskite Solar Cells.

Abstract

Inorganic cesium lead halide perovskite (CsPbX3) is a promising light-harvesting material to increase the thermal stability and the device performance as compared to the organic-inorganic hybrid counterparts. However, the photoactive stability at ambient conditions is an unresolved issue. Here, we studied the influence of Nb5+ ions' incorporation in the CsPbI2Br perovskite processed at ambient conditions. Our results exhibited that 0.5% Nb-incorporated CsPb1-xNbxI2Br (herein x = 0.005) thin films show excellent uniformity and improved grain size because of the optimum concentration of Nb5+ doping and hot-air flow. The improved grain size and uniform film thickness deliver a superior interface between the CsPb1-xNbxI2Br layer and the hole-transporting material. The fabricated all-inorganic perovskite solar cell (IPVSC) devices exhibited the Nb5+ cation incorporation which enables decreased charge recombination, leading to negligible hysteresis. The champion device produces an open-circuit voltage (VOC) as high as 1.317 V. The IPVSC device containing a CsPb0.995Nb0.005I2Br composition delivers the highest power conversion efficiency of 16.45% under a 100 mW cm-2 illumination and exhibits a negligible efficiency loss over 96 h in ambient conditions.