Efficient and fast remediation of soil contaminated by per- and polyfluoroalkyl substances (PFAS) by high-frequency heating

Abstract

This study presents a novel thermal technology (high-frequency heating, HFH) for the decontamination of soil containing per- and polyfluoroalkyl substances (PFAS) and aqueous film-forming foams (AFFFs). Ultra-fast degradation of short-chain PFAS, long-chain homologs, precursors, legacy PFAS, emerging PFAS was achieved in a matter of minutes. The concentrations of PFAS and the soil type had a negligible impact on degradation efficiency, possibly due to the ultra-fast degradation rate overwhelming potential differences. Under the current HFH experiment setup, we achieved near-complete degradation (e.g., >99.9%) after 1 min for perfluoroalkyl carboxylic acids and perfluoroalkyl ether carboxylic acids and 2 min for perfluoroalkanesulfonic acids. Polyfluoroalkyl precursors in AFFFs were found to degrade completely within 1 min of HFH; no residual cationic, zwitterionic, anionic, or non-ionic intermediate products were detected following the treatment. The gaseous byproducts were considered. Most of gaseous organofluorine products of PFAS at low-and-moderate temperatures disappeared when temperatures reached 890 °C, which is in the temperature zone of HFH. For the first time, we demonstrated minimal loss of PFAS in water during the boiling process, indicating a low risk of PFAS entering the atmosphere with the water vapor. The findings highlight HFH its potential as a promising remediation tool for PFAS-contaminated soils.