Efficient Adsorption Removal of Phosphate from Rural Domestic Sewage by Waste Eggshell-Modified Peanut Shell Biochar Adsorbent Materials.

Abstract

In order to promote the improvement of the rural living environment, the treatment of rural domestic sewage has attracted much attention in China. Meanwhile, the rural regions' sewage discharge standards are becoming increasingly stringent. However, the standard compliance rate of total phosphorus (TP) is very low, and TP has become the main limiting pollutant for the water pollutants discharge standards of rural domestic sewage treatment facilities. In this study, waste eggshell (E) was employed as a calcium source, and waste peanut shell (C) was employed as a carbon source to prepare calcium-modified biochar adsorbent materials (E-C). The resulting E-C adsorbent materials demonstrated efficient phosphate (P) adsorption from aqueous solutions over the initial pH range of 6-9 and had adsorption selectivity. At an eggshell and peanut shell mass ratio of 1:1 and a pyrolysis temperature of 800 °C, the experimental maximum adsorption capacity was 191.1 mg/g. The pseudo second-order model and Langmuir model were best at describing the adsorption process. The dominant sorption mechanism for P is that Ca(OH)2 is loaded on biochar with P to form Ca5(PO4)3OH precipitate. E-C was found to be very effective for the treatment of rural domestic sewage. The removal rate of TP in rural domestic sewage was 91-95.9%. After adsorption treatment, the discharge of TP in rural sewage met the second-grade (TP < 3 mg/L) and even first-grade (TP < 2 mg/L). This study provides an experimental basis for efficient P removal by E-C adsorbent materials and suggests possible applications in rural domestic sewage.