Efficient 1.53 μm erbium light emission in heavily Er-doped titania-modified aluminium tellurite glasses

Abstract

Ti–Al co-doped erbium tellurite glasses have been obtained by melting mixed Er 2O 3, TiO 2 and TeO 2 batches in Al 2O 3 crucibles. By crucible dissolution Al 2O 3 amounts from 11.5 to 18.6 mol% were introduced in the synthesized glasses. Differential thermal analysis of glasses points to a strong dependence of glass transition temperature T g with the substitution extent of TeO 2 by the doping oxides. No crystallization features are observed up to 450 °C. The spectral features and decay kinetics of the infrared photoluminescence of erbium demonstrate the possibility to achieve more than 50% of quantum yield of light-emission at Er 3+ concentrations as large as 10 21 cm −3, with about 2 ms of lifetime, 8 × 10 −21 cm 2 of stimulated emission cross section, and no saturation at pump power densities higher than 10 kW cm −2. The study of the kinetics of Er–Er energy transfer suggests to ascribe these features to a particularly homogeneous dispersion of Er 3+ ions in the modified tellurite network. Raman scattering measurements of the spectral distribution of vibrational modes evidence that the introduction of doping oxides leads to an increase of structural disorder without crystallization effects.