Abstract
A novel effervescence assisted on-site liquid phase microextraction has been developed for the determination of five triazine herbicides in water. The use of an effervescent tablet composed of citric acid, sodium bicarbonate and 1-undecanol (extraction solvent) was the core of the method. The triazine herbicides in water were extracted by 1-undecanol released from tablet under effervescence and determined by ultra-high pressure liquid chromatography tandem mass spectrometer. The experimental variables, including NaCl concentration, temperature, weight of effervescent tablet, volume of extraction solvent and pH value, were screened by a Plackett–Burman design and optimized by a Box–Behnken design. Under the optimized conditions, good linearity was obtained in the range of 0.05–10μgL−1 with correlation coefficients ranging from 0.9936 to 0.9988. The limits of quantification were between 7.6 and 26.4ngL−1, and the recoveries were in 71.4–93.2% with relative standard deviations of 2.5–10.9%. This method, which does not require centrifugation and any special apparatus, was successfully applied to determine triazine herbicides in real waters, promising to be a way to speed field sampling procedures for the organic pollutants monitoring in water.
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