Abstract
The effects of working-electrode potential on the rate of a controlled-potential electrolysis and on the quantity of electricity that eventually accumulates are discussed. In particular, it is proven that electrolysis at any potential where an appreciable current flows on a totally irreversible wave must proceed to virtual completion, and experimental confirmation of this prediction is given for the reduction of hydrogen ion on mercury electrodes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have