Abstract

AbstractThe increasing dependence on more robust additive chemistry to improve gear pitting resistance requires the additive technology development to rely less on a trial‐and‐error approach and more on a better basic understanding of the influence of additive chemistry on tribological contact layers' physical and chemical changes. The use of secondary neutral mass spectrometry (SNMS) and nanoindenter to analyse tribological contact layers had been carried out by Inacker and co‐workers at NMI. They found that the alkyl structure of zinc dithiophosphate (ZDTP) and the type of cation have a profound effect on the thickness and nanohardness of the tribological layer. An extension to that study has been carried out in this investigation, which involves a design experiment of two variables (oil viscosity and surface roughness) while keeping the additive chemistry constant to determine their impact on the tribological layer. The methods used to analyse the tribological layers include SNMS, nanoindenter and SEM coupled with focused ion beam imaging of the rectangular well‐shaped cross section. The results in general are in agreement with the findings of Inacker and his co‐workers, namely greater micropitting reduces the thickness of the tribological layer and brings closer the depth of nanohardness maximum to the surface. Copyright © 2006 John Wiley & Sons, Ltd.

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