Abstract

The Kermadec Arc-Backarc system (25–39°S) in the southwest Pacific is an important natural laboratory to examine the controls on arc magma compositions, because the physical parameters that are thought to influence subduction-related magmatism (the thickness and composition of the upper plate, mantle depletion and partial melting, and the slab components) change along the arc. Furthermore, the presence of back-arc and rear-arc volcanism allow insight into how mantle composition varies with distance to the trench. We present new major and trace element and Pb–Sr–Nd–Hf isotope data for 101 lava samples from 10 volcanoes along the Kermadec Arc, and combine these with published data for volcanic arc front, rear-arc, and back-arc lavas. The Kermadec Arc-Backarc magmas experienced similar fractional crystallization paths, and those erupted onto oceanic crust are not affected by crustal assimilation. The degree of partial melting varies along and across the arc, partly due to variations in the thickness of the lithosphere of the upper plate, but also due to variations in slab fluid input. We distinguish four different arc segments varying from 100 to 600 km wide, which erupt lavas with distinct compositions due to differences in along-arc slab input. All Kermadec arc and rear-arc lavas were derived from mantle sources to which the sediment melt and a fluid from subducted Pacific oceanic crust or the Hikurangi Seamounts had been added. Increasing sediment melt input into the mantle wedge southwards is reflected in increasing 87Sr/86Sr and Th/Nd, and decreasing 143Nd/144Nd southwards towards New Zealand. Some volcanoes from the central Kermadec Arc show with unusually radiogenic Pb isotope compositions that are probably derived from subducted alkaline rocks from seamounts built on the Hikurangi Plateau. The geochemical segmentation of the Kermadec Arc indicates that slab-derived components can be relatively homogeneous on large scales, but small features like seamounts cause complex additions to the slab component.

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