Effects of vapor-phase deposition processes on the optical, chemical, and magnetic properties OE the lunar regolith

Abstract

The processes of solar wind sputtering and meteoritic impact vaporization have created materials in the lunar regolith which were deposited from a vapor phase. Although the quantity of such exotic condensed substances should theoretically be comparable with that of materials which have been melted by impacts, their existence in the fines has not been generally recognized. We have investigated the physical and chemical properties of materials deposited from vapors generated by hydrogen-ion sputtering and thermal evaporation of lunar and artificial ferrosilicates. Both processes are highly reducing. The deposits are enriched in Fe, have large, nonselective, optical absorptivities, and contain abundant sub-microscopic, superparamagnetic grains of metallic Fe which exhibit the characteristicg=2.1 ESR resonance. The sputter-deposited films are enriched in heavy elements. Thus the hypothesis that the lunar fines contain several percent of materials deposited from the vapor phase accounts in a natural manner for many of the unusual optical, physical and chemical properties of lunar soils. The vapor-deposits are probably concentrated in the agglutinate particles of the regolith.