Effects of UV sensitivity and accelerated photo-aging on stab resistance of ρ-aramid fabrics impregnated with shear thickening fluids (STFs)

Abstract

The use of Kevlar in the field of ballistic and stabbing protection has been studied by researchers in polymeric composites for this purpose. This study presents complementary knowledge on energy absorption and dissipation in ρ-aramid fabric impregnated with shear thickening fluids (STFs), especially aiming to obtain better protection against impacts that are deeply associated with STFs, as well as color change, accelerated aging (QUV), and penetration depth (drop tower test). In addition, Scanning Electron Microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) was performed. The research shows that there was a good distribution of STF particles on the ρ-Aramid fabric surface, promoting increased friction between the interfilament and the yarns, further increasing performance and, consequently, improving the energy absorption and dissipation mechanism and, also, the penetration effectiveness in relation to non-impregnated ρ-Aramid fabric. Regarding the protection efficiency against UV exposure (250–400 nm region), there was a significantly decreased compared to those non-impregnated Kevlar® woven with STFs. The FTIR analysis showed that the conditions of aging, after exposure to UV, did not produce new functional groups, that is, there was no chemical modification. Finally, Kevlar fabric impregnated with STFs improved penetration depth performance with the blades independent of the blade type with up to 81% increase in resistance. This result was improved due to interactions between the nanoparticles present in STFs, yarns, and even high-performance woven impregnated with shear-thickening fluids.