Effects of urea concentration and reaction temperature on morphology of gadolinium compounds prepared by homogeneous precipitation

Abstract

Europium-activated Gd 2O 3 phosphor powders were prepared by homogeneous precipitation method, and the effects of urea concentration and reaction temperature on the morphology of precursor powders were investigated. The synthesized powders were characterized by means of XRD, SEM, TG/DTA and FT-IR. The synthesis of gadolinium carbonate compounds was carried out using this method from relatively high concentrations of gadolinium salt and urea for the first time. Two kinds of powders formed were the crystalline Gd 2(CO 3) 3·2.5H 2O and Gd 2O(CO 3) 2·H 2O phases, which were mainly affected by reaction temperature. Namely, the Gd 2(CO 3) 3·2.5H 2O phase was formed at 80–90 °C, and the Gd 2O(CO 3) 2·H 2O at 100 °C. The morphology of Gd 2(CO 3) 3·2.5H 2O phase was plate-like. And the powders of Gd 2O(CO 3) 2·H 2O phase showed the rectangular plate-like morphology. In order to synthesize the nanometer-sized precursor powders using the homogeneous precipitation technique, it was found that EDTA/[Gd + Eu] mole ratio should be larger than 7.5 × 10 −3 M, corresponding to 15 mol% of total cation concentration. The nanometer-sized precursor showed the amorphous-like pattern. The thermal decomposition behaviors of the three kinds of gadolinium carbonate compounds were also investigated. The thermal stability had the following order: Gd 2O(CO 3) 2·H 2O > Gd 2(CO 3) 3·2.5H 2O > amorphous phase.