Abstract
A model is presented for uniaxial-stress-induced alterations in the intrinsically strainbroadened line shapes for magnetic-resonance absorption within a non-Kramers doublet for the point-group symmetries ${D}_{3d}$, ${C}_{3v}$, and ${O}_{h}$. (The term doublet is used here to denote the $|\ensuremath{\Delta}{M}_{s}|=2$ transition within a ground triplet.) The uniaxial stress is introduced as boundary conditions in the model for the intrinsically strain-broadened line shapes for non-Kramers doublets given previously. The effects of uniaxial stress are considered for the EPR where the local site symmetry is ${O}_{h}$ and ${D}_{3d}$. For the local symmetry ${C}_{3v}$, the effects of uniaxial stress are considered for the paraelectric resonance absorption. The model provides a means for evaluating the strength of the spin-lattice coupling from uniaxial-stress experiments, independent of the concentration of the paramagnetic impurity ions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.