Abstract
The excitation conditions in inductively coupled plasmas (ICPs) loaded with organic solvents of widely different nature has been investigated. The axial distribution of the excitation temperature, obtained from iron ionic line intensities, the spatial distribution of C 2,C and CN emission, and the axial distribution of analyte emission were established for ICPs loaded with equal numbers of solvent molecules as well as for ICPs loaded with equal amounts of carbon. It was found that both the nature of the solvent and the solvent plasma load are decisive for the excitation conditions in “organic ICPs”.
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