Effects of the cure cycle and thermoplastic content on the final properties of dicyanate ester/polysulfone Semi-IPNS

Abstract

A bisphenol A dicyanate resin, BADCy, was toughened by incorporating polysulfone, PSU, at various compositions. The catalyst system used was a mixture of copper acetylacetonate and nonylphenol. Phase separation and rheokinetics were studied through curing. The blends seemed to have a LCST behavior, and the presence of PSU did not affect the polycyclotrimerization kinetics. The phase structure, thermal, and mechanical properties of the final network were investigated as a function of the PSU content and cure temperature. The toughness of the BADCy/PSU blends was closely related to their final morphology, increasing with the amount of phase inversion. The mechanical properties were not affected by the addition of the thermoplastic. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1799–1809, 2002