Effects of surfactants on rheological properties of a dispersed viscoelastic microsphere

Abstract

ABSTRACTThe swelling ratio is an important performance for the application of viscoelastic microsphere. The reduction of swelling ratio can affect the particle size. The compatibility between particle size and formation pore can affect the plugging performance and EOR capability. Adsorption characteristics of cationic surfactant cetyltriethylammnonium bromide (CTAB), anionic surfactant petroleum sulfonate applied in GangXi oilfield (GXPS), and nonionic surfactant nonylphenol ether (TX‐10) onto viscoelastic microspheres and the effect of the three types of surfactant on swelling ratio of viscoelastic microspheres were investigated. Effects of surfactants on rheological properties of viscoelastic microspheres were researched in two different modes referring to steady shear and dynamic shear, respectively, using Physica MCR301 Rheometer. The results showed that the interactions between viscoelastic microsphere and surfactants CTAB were electrostatic attraction and hydrophobic association, that the interaction between viscoelastic microsphere and surfactants TX‐10 was just hydrophobic association, and that the interactions between viscoelastic microsphere and GXPS were electrostatic repulsion and hydrophobic association. At the same initial surfactant concentration, all these three types of surfactant could be adsorbed onto the surface of viscoelastic microspheres and reduce its swelling ratio and storage modulus. Because of different amount of adsorption, the extent of reduction order on swelling ratio and storage modulus was CTAB>TX‐10>GXPS. In addition, the yield stress of viscoelastic microspheres which was obtained from modeling the data to Herschel‐Bulkley model decreases with the increase of surfactant adsorption. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42278.