Abstract
The objective of this study is to provide a method which allows introduction of functional groups onto silk cocoon surface. Plasma irradiation is straight-forward, relatively noninvasive and requires minimal chemical reaction steps to alter surface hydrophilicity of polymeric materials. Introduction of oleic acid on pristine and air-zero irradiated silkworm (Bombyx mori) cocoons was carried out via acid-catalyzed esterification. The reaction was confirmed by ATR-FTIR spectroscopy. Functionalization of oleic acids onto silkworm cocoons favors hydrophilic surface. In addition to the acid-catalyzed esterification, amide hydrolysis takes place as a side reaction. This reaction leads to formation of hydrophilic carboxylic acids and amines. The change in hydrophilic functionalities leads to an increase in cocoon wettability as confirmed by contact angle measurements.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
