Effects of Substrate Surface Characteristics on the Adhesion Properties of Geopolymer Coatings.

Abstract

Geopolymer is a kind of material with a better ability of high-temperature and corrosion resistance. Poor adhesion could easily lead to problems such as coating cracks, peeling at an early stage, and inability to work with the substrate. The adhesion depends on many factors such as chemical composition of the raw materials, the formulation of the geopolymer, the type of substrate, surface roughness of the substrate, etc. The higher the Si/Al ratio, the greater the shear strength of the coating. This is because geopolymers synthesized with different Si/Al ratios have different phases in the geopolymer binder. Each study uses different multi-parameter combinations selected by itself, which is not uniform and has no universal applicability. As the parameter Ra is determined by the profile centerlines of the substrate surface, it is difficult to get an appropriate value of Ra to represent the roughness of the substrate surface. The parameter-relative area, determined by area scale fractal analysis, can effectively characterize the surface roughness, predict the texture component of bond strength, and establish a connection between which and the bonding performance of the geopolymer coating at a high level of confidence. The bonding strength reduces with the decrease in the value of the relative area. The magnitude of scale employed should be seriously determined when characterizing the surface roughness.