Abstract

The influence of industrial oilseed extraction methods on the quality and stability of crude sunflower oil (pre-pressed, solvent-extracted, full-pressed and mixed oils) was studied by means of the determination of free fatty acids, peroxide value, color value, iron, phosphorus, total and individual tocopherol contents, their stability against oxidation (Rancimat induction time) and the fatty acid composition with special emphasis on trans fatty acids. In addition, these crude oils were stored for a period of four months at 40 ± 2°C and analyzed at monthly intervals for free fatty acids, peroxide value, and Rancimat induction time to evaluate their storage stability. The results revealed that the crude sunflower oils obtained by the full-pressed extraction method had worse quality and stability parameters than the crude oils obtained by other extraction methods. Tocopherol content showed a drastic decrease with full-pressed extraction. Also, the crude sunflower oils obtained by the full-pressed extraction presented a higher total trans fatty acid content than the others. On the contrary, the solvent extraction method influenced the phosphorus and iron contents more than the others. The results indicated, however, that pre-pressing the oil appeared to be better than other methods. This study suggests that it is absolutely necessary for the vegetable oil industry to reevaluate the full pressing method as well as the solvent extraction conditions used for sunflowerseeds in order to retain both nutritive value and oxidative stability.

Highlights

  • Crude vegetable oils are traditionally refined by physical or chemical processes

  • The results demonstrated an important difference in the some quality and stability characteristics among the studied crude sunflower oils due to different industrial oilseed extraction methods employed

  • The effect of the full pressing method exceeded that of the others with respect to influence on the fatty acid composition, tocopherols, free fatty acid, peroxide value, Rancimat stability and color value

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Summary

Introduction

Crude vegetable oils are traditionally refined by physical or chemical processes. The objective of refining is to eliminate impurities with the least possible effect on desirable components present in the crude vegetable oils in order to obtain an odorless, bland and oxidatively stable refined vegetable oil that is acceptable to consumers (Ferrari et al, 1996; Medina-Juarez et al, 2000). Acceptable quality characteristics of crude vegetable oils processed by refining methods are of crucial importance in order to obtain such refined vegetable oils. Most crude vegetable oils conventionally have been obtained from oilseeds by either mechanical pressing or solvent extraction methods. Solvent oil extraction is usually applied to seeds with low oil content ( 20%), such as soybeans (Azadmard-Damirchi et al, 2010). The quality characteristics of crude vegetable oils obtained by

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