Abstract
Soil components, solution chemical properties, and temperature are important factors that affect Cu(II) adsorption in soil. However, the research in this area is currently lacking. In this study, the clay fraction was separated from alluvial acid soil. In addition, organic matter, free Fe oxides, and Mn oxides were selectively removed by washing the bulk soil and the clay fraction with H2O2, Na3C6H5O7·2H2O + NaHCO3 + Na2S2O4, and HONH3Cl. Adsorption experiment results indicate that Cu(II) adsorption decreased for bulk soil and clay fractions after removing organic matter and Mn oxides. However, after free Fe oxides were removed, the Cu(II) adsorption increased for bulk soil and clay fractions. The adsorption capacity of the clay fraction for Cu(II) was higher than that of the bulk soil irrespective of the selective chemical extraction treatment. When the initial pH increased from 2 to 3.5, the adsorption capacity increased rapidly; when the pH > 6, the adsorption capacity did not change significantly. When the pH was greater than 6, increased Cu(II) adsorption may occur due to the precipitation of Cu(II). Increased ionic strength can inhibit Cu(II) adsorption. The effects of foreign ions on Cu(II) adsorption were in the order Na+ < K+ < Mg2+ < Ca2+ for cations and NO3− < SO42− ≈ Cl− for anions. The Cu(II) adsorption was an endothermic and spontaneous process under the investigated experimental conditions.
Highlights
Cu is an abundant element in the lithosphere
Clay fraction was separated from an alluvial acid soil, the selective chemical extraction method was used to remove the specific components in the bulk soil and clay fraction
Adsorption experiments showed that the adsorption capacity of the clay fraction of Cu(II) is greater than that of the bulk soil, regardless of whether it is treated by selective chemical extraction or not
Summary
Cu is an abundant element in the lithosphere It is an essential metal for plant nutrition (He et al, 2005). The solubility of copper in soil solutions is controlled by adsorption/desorption, complexation, and precipitation. These interactions determine the mobility and bioavailability of Cu(II) in soil and water environments (Silveira et al, 2003; Violante et al, 2010). Because of the differences in specific surface area, Fe/Mn/Al oxides and organic matter contents (Acosta et al, 2009; Bi et al, 2013), the adsorption capacity of various particle size aggregates is different (Acosta et al, 2011); this property depends on the heavy metal/metalloid species (Huang et al, 2017)
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