Effects of Silicone Surfactant on the Properties of Open‐Cell Flexible Polyurethane Foams

Abstract

ABSTRACTIn this paper, the effects of silicone surfactant on the mechanical, thermal, and acoustical properties of flexible polyurethane foams are studied. At first, by introducing the reactions of the foam production and expressing the stoichiometric relationships, a method is provided to select the amounts of the basic compounds for getting the desirable properties. By knowing the OH number of polyol and the NCO content of isocyanate after selecting an amount of a blowing agent for the reaction, the quantity of each compound to produce the desirable foam can be found. Then different foams with various amounts of surfactant are produced. By preparing proper samples, the mechanical, thermal, nonacoustical, and acoustical properties of the foams are measured or calculated by using different instruments. The nonacoustical properties are obtained based on two distinct methods, i.e., a semiphenomenological method and an indirect method. The obtained properties are validated by comparing the calculated theoretical sound absorption coefficients with the measured ones. The results show that with a small increase of surfactant, the acoustical properties of foam samples improve by about 50% without any significant changes in other mechanical and thermal properties of the foams. This improvement results from the variations of reticulation rate and cell size. In addition, the initial desirable porosity and density considered in the stoichiometric relations are fairly achieved in produced samples. These results validate the accuracy of the stoichiometric relations.