Effects of side chain length on the performance of poly(aryl-alkylene) anion exchange membranes for fuel cells

Abstract

Anion exchange membranes (AEMs) are one of the most critical materials determining the fuel cell (FC) performance. From current reports, there are still many limit factors for AEMs, such as conductivity, mechanical performance, power density and durability, which greatly affect their practicality. Here, we introduce a range of arylfluoroketone monomers with different side chain lengths into the poly (aryl-alkylene) matrix material using a copolymerization strategy to get AEMs. This study aims to investigate the effect of side chain length on the performance of AEMs, such as phase separation, ion conductivity and mechanical properties. Due to the existence of long alkyl side chains, QTPNPC4 shows significant hydrophilic aggregation, outstanding OH− conductivity (158.6 mS cm−1, 80 °C) and excellent flexibility (109.1 %). Meanwhile, QTPNPC4 exhibits remarkable ex-situ durability (96.3 %) and chemical stability (96.6 %) after soaking in a 2 M NaOH solution for 1560 h at 80 °C. In addition, the peak power density (PPD) of a single cell with QTPNPC4 reaches 927 mW cm−2 (80 °C), and the membrane has good in-situ durability (0.689 mV h−1).