Effects of Road Salts on Heavy Metal Mobility in Two Eastern Washington Soils

Abstract

Heavy metals deposited on road surfaces and transferred to roadside environments by rainfall and snowmelt runoff can have serious impacts on receiving ecosystems. Infiltration is an effective best management practice for controlling metal contamination in runoff, although metals retention within infiltration facilities depends on a number of factors, including metal species, soil characteristics, and influent water quality concentrations. In cold climates, deicing compounds have been shown to mobilize heavy metals putting receiving waters at risk. This study ascertains the effects of two widely used road salts (NaCl and MgCl 2 ) on heavy metal mobility in two eastern Washington soils. Infiltration experiments were conducted using a basic soil, exhibiting a soil pH of 8.3, taken from a highway infiltration pond site in Spokane Washington and an acidic soil, exhibiting a soil pH of 5.9, taken from an infiltration pond site in Richland Washington. Three concentrations of each salt were percolated through both soils using continuous flow soil columns. Leachate samples were collected and analyzed for dissolved metals, organic matter, and pH. Experiments were also performed without salt and used as controls. Results indicate that metal mobilization can occur by a number of mechanisms including cation exchange, chloride complex formation, and colloid dispersion (release of organic matter and/or clay that can complex metal species). Sodium chloride resulted in the largest release of copper and lead via indirect mobilization of organic matter. The magnesium salt had less of an effect on lead and copper but had a much greater effect on the mobilization of cadmium. Releases of metals during or immediately following salt application produced concentrations that ranged from 50% to 1000% greater than the concentrations released from the control experiments.