Effects of recharge process on groundwater nitrate concentration in an oasis of Tengger Desert hinterland, China.

Abstract

Groundwater nitrate concentrations cannot be effectively diluted in an oasis of desert hinterland without direct recharge from external rivers. Therefore, there is an urgent need to understand the relationship between groundwater nitrate concentration and the groundwater recharge process. Using hydrochemicals, stable isotopes, LUCC, and combining these with the MixSIAR model, the distributions of groundwater nitrate concentration in the Dengmaying Basin (DMYB) in 2006 and 2020 were obtained. The contributions of groundwater recharge and nitrate sources were also quantified. With the development of agriculture in the DMYB, groundwater irrigation leakage has gradually become a crucial recharge source of groundwater, with a recharge proportion reaching 30.3%. From 2006 to 2020, under the influence of well irrigation and agricultural fertilization, the groundwater nitrate concentration in the DMYB increased significantly, with an increased range of 1.3 ~ 14.3mg L-1. Moreover, the δ15N-NO3- and δ18O-NO3- values of nitrate in cultivated soil water were similar to those in groundwater, which also proves the process of carrying nitrate from the vadose zone into groundwater by irrigation water. The contribution of anthropogenic sources (54.9%) to groundwater nitrate exceeded that of natural sources (45.1%) to groundwater nitrate in the DMYB. These results indicate that the potential for nitrate pollution in groundwater must be considered, even in desert oases.