Abstract
In this work, effects of rare earth elements on microstructure evolution and wear properties of TiB2 reinforced aluminum matrix composite coatings were investigated by the combination of first principles calculations and experimental investigation. The calculated results revealed that Sc exhibited the most effective modification ability due to the most negative adsorption energy and the largest charge transfer compared with La and Y. Based on the calculated results, the rare earth elements modified composite coatings were synthesized by laser processing. The as-obtained composites were characterized by back-scattered electron imaging (BSE) and spherical aberration corrected scanning transmission electron microscopy (Cs-corrected STEM). Results indicated that the addition of Sc can greatly refine the particle size of TiB2, improve the distribution of particles and lead to the morphology transforming from hexagonal disk to sphere. As a result, the microhardness and wear properties of the composite coatings were enhanced significantly. The best properties were achieved in the composite with 0.6 wt% Sc addition, which exhibited highest microhardness of 920 HV, lowest friction coefficient of 0.4 and wear rate of 24.8 mg /h. The preferential adsorption of rare earth elements on TiB2 facets is proposed to be the main modification mechanism which results in the morphology evolution and wear properties improvement.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
