Abstract

Reinforcing polyoxymethylene (POM) with glass fibers (GF) enhances its mechanical properties, but at the expense of tribological performance. Formation of a transfer film to facilitate tribo-contact is compromised due to the abrasiveness of GF. As a solid lubricant, for example, polytetrafluoroethylene (PTFE) significantly improves friction and wear resistance. The effects of chemically etched PTFE micro-particles on the fiber-matrix interface of POM/GF/PTFE composites have not been systematically characterized. The aim of this study is to investigate their tribological performance as a function of micro-PTFE blended by weight percentage. Samples were prepared by different compositions of PTFE (0, 1.7, 4.0, 9.5, 15.0 and 17.3 wt.%). The surface energy of PTFE micro-particles was increased by etching for 10 min using sodium naphthalene salt in tetrahydrofuran. Tribological performance was characterized through simultaneous acquisition of the coefficient of friction and wear loss on a reciprocating test rig in accordance to Procedure A of ASTM G133-95. Friction and wear resistance improved as the micro-PTFE weight ratio was increased. Morphology analysis of worn surfaces showed transfer film formation, encapsulating the abrasive GF. Energy dispersive X-ray spectroscopy (EDS) revealed increasing PTFE concentration from the GF surface interface region (0.5, 1.0, 1.5, 2.0, 2.5 µm).

Highlights

  • Polymer composites are physical mixtures of a polymer, known as the matrix, and a reinforcing filler, called the dispersed phase

  • Friction and wear behavior of POM composites filled with glass fibers (GF) and PTFE

  • The study examined the mechanism of PTFE to effectively enhance tribological properties through transfer film formation

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Summary

Introduction

Polymer composites are physical mixtures of a polymer, known as the matrix, and a reinforcing filler, called the dispersed phase. The latter is added to enhance mechanical, tribological or other properties [1]. Thermoplastics and thermosets are the two types of matrix used in this class of composites. The reinforcing fillers can be organic or inorganic, in the form of fibers or particles. The important types of polymer-based composites (PBCs) contain fibers, particles, or a combination of both [2]. The matrix and reinforcement are separated by an interphase, a term introduced in the

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