Abstract
In order to improve the high-rate partial-state-of-charge (HRPSoC) performance of lead-acid batteries for hybrid-electric vehicles, graphene oxide (GO), polypyrrole (PPy) and three PPy/GO composites with different weight ratio of pyrrole to GO (mpy/mGO) were selected as additives to form negative plates and simulated test cells. The effects of these additives on the electrochemical performance and the microstructure of the negative plate and on the HRPSoC cycle performance of the simulated test cell were investigated. The results indicate that the microstructure of the negative plate is changed with the addition of different additives. GO significantly increases the hydrogen (H2) evolution ability of the negative plate, while PPy has the opposite effect. The incorporation of the proper content of PPy with GO can effectively inhibit the H2 evolution of the negative plate. Moreover, adding different additives in the negative plate also decreases its total impedance, accelerates the redox processes between Pb and PbSO4 on it and increases its specific capacitance. GO and the PPy/GO composite with mpy/mGO=1:1 (PG1) can significantly increase the HRPSoC cycle life of the simulated test cell. Considering the H2 evolution performance and the HRPSoC cycle performance, the PPy/GO composites with a medium mpy/mGO ratio, such as PG1, may be the appropriate additives for the negative plate of lead-acid batteries.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
