Abstract

The aim of this work was to improve the ambient temperature ionic conductivity of poly(ethylene oxide) (PEO) complex electrolytes. The effects of various plasticizers, such as poly(ethylene glycol) (PEG), monomethoxy poly(ethylene glycol) (MMPEG), dimethoxy poly(ethylene glycol) (DMPEG), were examined. Considering the compatibility between the polymer electrolytes and lithium anode, lithium-treated poly(ethylene glycol) (LPEG) was mainly used as the plasticizer blended into the PEO-LiCF 3SO 3 complex electrolyte. Conductivities of PEO-based polymer electrolytes are enhanced three orders of magnitude at room temperature.

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