Abstract
Understanding the influence of organic matters on the fate of Cr(VI) during ferrihydrite-Cr(VI) (Fh-Cr) co-precipitates transformation helps to study the retention of Cr(VI) by iron oxides in the environment. In this paper, Fh-Cr was prepared by co-precipitation and the redistribution of Cr(VI) in the oxalate or citrate system during the transformation of Fh-Cr was studied. X-ray diffraction, Fourier transform infrared spectroscopy, Transmission electron microscopy, and X-ray photoelectron spectroscopy were used to characterize Fh-Cr for aging 7 days at 70 °C. Results showed that both oxalate and citrate could hinder the release of Cr(VI) from Fh-Cr and abate the harm of Cr(VI). Oxalate improved the transformation from Fh-Cr to hematite and promoted Cr(VI) to be enfolded into the secondary minerals to further immobilize Cr at initial pH of 5.0 and 7.0, while citrate evidently reduced the release of Cr(VI) through stabilizing Fh-Cr at initial pH of 9.0. Besides, reduction of Cr(VI) by oxalate and citrate was through forming the surface complexes that promoted electron transfer from oxalate or citrate to Cr(VI), which can effectively abate the harm of Cr(VI). The findings of this study can promote understanding of the influences of organic matters on Cr(VI) immobilization during transformation of iron oxides in nature.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.