Effects of Organic Maceral on Biogenic Coalbed Gas Generation from Bituminous Coal.

Abstract

Clarifying the effect of organic maceral on biogenic coalbed gas generation is important to understand the mechanism of biogenic coalbed gas generation and to develop bioengineering of coalbed gas. Bituminous coals in the Huainan mining area of China were selected as the research object, and the organic macerals were enriched through manual separation and floatation–sedimentation experiments first. Then, the simulated biogas generation experiments were carried out by using raw coal, single vitrinite, and inertinite, respectively. The results showed that all the bituminous coal, vitrinite, and inertinite could be biodegraded to generate biogas. The gas production yield of vitrinite was11.5 mL/g, which was more than that of raw coal (9.8 mL/g) and inertinite (6.26 mL/g). The production processes showed the stage characteristics of rapid increase and continuous decrease, but the gas production peak of inertinite lagged behind that of raw coal and vitrinite. Vitrinite content was positively correlated with total gas production, while inertinite could inhibit biogas production. CH4 composition in simulated biogas from vitrinite was the most, and that from inertinite was the least, while there was a positive correlation between vitrinite content and CH4 composition. The above evidence showed that vitrinite in bituminous coal is more easily biodegradable. There were significant positive correlations between chloroform bitumen “A”, H, and H/C to total gas production, and they can be used as important indicators to evaluate the output of coalbed biogas.