Abstract

Zirconium oxide nodules formed on BWR fuel rods were characterized quantitatively and correlated statistically with the rod operational parameters. Cladding specimens were obtained from fuel rods irradiated in a commercial BWR. Their burnup and fast neutron fluence ranged 17~38 GWd/t and 4×1025~8×1025 n/m2, respectively. Characteristic variables of the nodules such as maximum thickness T max (μm) were measured on metallographs of the cladding cross sections. These variables were correlated by multiple regression analyses with the operational parameters, such as irradiation time t (d), linear heat rate p (kW/m) and fast neutron flux ø (n/m2-s). For example, the maximum thickness depended on linear heat rate and showed a saturating tendency with burnup B (GWd/t) (Tmax ∝ t0.8+0.5 p2.3±0.9 or T max ∝B0.8+0.4p1.5±0.5). This decrease of growth rate with irradiation time was interpreted in terms of a microstructure change of Zircaloy-2 during neutron irradiation. Results of transmission microscopy and energy dispersive X-ray spectroscopy indicated that the alloying elements such as Fe, Cr and Ni dissolved from intermetallic precipitates into the base metal during neutron irradiation. Dissolution of the alloying elements might be effective in decreasing the growth rate of nodules.

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