Abstract
Nb promoter was introduced in the Co–CeO2 catalyst to improve its catalytic performance in the high temperature water gas shift (HT-WGS) reaction, which involves the production of hydrogen from waste-derived synthesis gas. Thereafter, the physicochemical properties of the promoter as well as those of the catalyst were investigated using various techniques. Thus, it was confirmed that the Nb promoter affects the key properties related to catalytic performance, including oxygen storage capacity (OSC) and dispersion. To maximize the positive effect of the Nb promoter, we further investigated the effect of the Nb loading amount on the performance of the catalyst. The results obtained showed that the 1.5NbCo catalyst exhibited the highest catalytic performance (XCO = 89% at 450 °C) under very severe conditions (gas hourly space velocity (GHSV) = 637,320 h−1). Additionally, this catalyst exhibited stable activity for 50 h. This its high catalytic performance could be attributed to its high OSC and Co dispersion. Therefore, it is a promising catalyst for hydrogen production via the HT-WGS reaction.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
