Abstract
Effects of NaN3 added in Fe—C system to synthesize nitric diamond at high pressure and high temperature are investigated. Diamond crystals with high nitrogen concentration are synthesized by the system of Fe—C and NaN3 additive at pressure 5.8 GPa and at temperatures 1750–1780K for 15 min. The synthetic diamond crystals have a cubo-octahedral or octahedral shape with yellowish green or green colour. Some disfigurements are observed on the surfaces of most diamond crystals. The composition and content of inclusions formed by iron in diamond are changed and iron nitride is detected in diamond crystals synthesized with Fe–C–NaN3 additive. As the amount of NaN3 additive increases, Fe3 C decreases and iron nitride increases with α-Fe being nearly constant. Moreover, the nitrogen concentrations in diamond crystals synthesized with 1.5wt% NaN3 additive is up to 2250 ppm in substitutional form.
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