Abstract

The high production rate of conventional plastics and their low degradability result in severe environmental problems, such as plastic accumulation and some other related consequences. One alternative to these materials is the production of oil-free bioplastics, based on wastes from the agro-food industry, which are biodegradable. Not only is rice bran an abundant and non-expensive waste, but it is also attractive due to its high protein and starch content, which can be used as macromolecules for bioplastic production. The objective of this work was to develop rice-bran-based bioplastics by injection moulding. For this purpose, this raw material was mixed with a plasticizer (glycerol), analysing the effect of three mould temperatures (100, 130 and 150 °C) on the mechanical and microstructural properties and water absorption capacity of the final matrices. The obtained results show that rice bran is a suitable raw material for the development of bioplastics whose properties are strongly influenced by the processing conditions. Thus, higher temperatures produce stiffer and more resistant materials (Young’s modulus improves from 12 ± 7 MPa to 23 ± 6 and 33 ± 6 MPa when the temperature increases from 100 to 130 and 150 °C, respectively); however, these materials are highly compact and, consequently, their water absorption capacity diminishes. On the other hand, although lower mould temperatures lead to materials with lower mechanical properties, they exhibit a less compact structure, resulting in enhanced water absorption capacity.

Highlights

  • Nowadays, research and development of biopolymers has grown due to the increasing interest in using renewable and natural sources in the polymer processing industry

  • There is a remaining percentage, accounting for 46.45% of the sample, which can be attributed to carbohydrates

  • The results obtained in this work support the suitability of rice bran (RB) to develop bioplastics obtained by injection moulding

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Summary

Introduction

Research and development of biopolymers has grown due to the increasing interest in using renewable and natural sources in the polymer processing industry. This is a consequence of the depletion of oil reserves and the serious environmental issues caused by plastic accumulation. Biopolymers can be divided into two categories: biodegradable polyesters, which are petroleum-based yet biodegradable, and polymers from renewable sources, such as protein and starch-based biopolymers, which are produced from natural sources and are readily biodegradable [1]. Biodegradable polymers can make significant contributions to material recovery (producing high added value products), reduction of landfill and utilization of renewable resources [4]

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