Effects of microstructure on the corrosion behavior of pearlitic rail steel under simulated salt fog conditions

Abstract

In this paper, the corrosion resistance and mechanisms of rail specimens with different lamella spacings in a salt spray environment were evaluated and investigated. This investigation was achieved by controlling different cooling rates of pearlitic bodies through heat treatment to obtain various lamella spacings. The results indicated that the corrosion resistance of all the specimens decreased during the salt spray test. The specimens with slow cooling rates (resulting in large pearlitic sheet layer spacings) had poorer corrosion resistance than those with fast cooling rates. Specimens obtained with both fast and slow cooling rates (air cooling at a 0.01 °C/s cooling rate) displayed similar corrosion patterns. However, the corrosion stability of the specimen obtained at a cooling rate of 0.03 °C/s fluctuated considerably after 144 h of salt spray corrosion. This fluctuation was attributed to the transformations of corrosion products within the rust layer. The structural stability of the rust layer was related to the defects present in the material. Large defects increase the instability of the rust layer, thereby increasing the susceptibility to corrosion in a salt spray environment.