Abstract
The effect of an ionic (SDS) and two nonionic (TX-100 and Tween 20) surfactants on the electron transfer reaction between l-leucine and gold(III) complexes has been investigated in acetate buffer. H+, Cl–, and decreasing dielectric constant of the medium have inhibiting effects on the reaction rate. The reaction product has been identified as isovaleraldehyde by 1H NMR. Two different Au(III) species and the zwitterion form of the amino acid react where Au(III) undergoes a one step two-electron transfer process. In the presence of surfactants, the postmicellar kinetics has been explained in the light of Berezin’s model where both the oxidant and the substrate are solubilized in the micellar pseudophase and then react. The leucine molecules occupy the hydrophobic core of the micelle with the polar amino and acid groups projected in the Stern/palisade layer among the surfactant head-groups and the oxidant species. The binding constants for substrate–micelle association and the corresponding enthalpy changes ...
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