Abstract
The AB5-type M1Ni3.5Co0.6Mn0.4Al0.5 alloy (where M1 denotes mixed lanthanide) was modified with different additives (ZnO and MnO2), and the effects of metal oxides on the electrochemical properties of the M1Ni3.5Co0.6Mn0.4Al0.5 − x% M (x = 5, 10; M = ZnO, MnO2) alloy were studied. The results showed that the addition of metal oxides had a positive effect on the activation property of the alloy electrode. With the addition of ZnO, the maximum discharge capacity of the alloy increased from 315 to 334 mAh/g (x = 5) and 341 mAh/g (x = 10) with good cycle capability (C30/Cmax) (87% for x = 5 and 85% for x = 10), while the maximum discharge capacity remained invariable and the cyclic stability was deteriorated by the addition of MnO2. Linear polarization (LP), cycle voltammetry (CV), and electrochemical impedance spectroscopy (EIS) measurements were also performed to investigate the electrochemical kinetics of alloy electrodes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
