Abstract

It is commonly accepted that contour length fluctuations increase the viscosity exponent for chains that diffuse by reptation. We found that length fluctuations in the necklace model can play an unexpected role as they can also decrease this exponent. A detailed analysis of the interplay between the discrete character of the model and how the fluctuations take place is presented in this work. Basically, we found that when fluctuations are symmetric their influence is the expected one; when fluctuations are not symmetric new effects can appear.

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