Abstract
Both LaF3 and the in situ formed LaH2 enable the reversible hydrogen sorption in NaBH4. Comparative studies show that La-B phases play the major role for the regeneration of NaBH4 in both the NaBH4+LaF3 and the NaBH4+LaH2 composites while the substitution of F- for H- results in more favorable thermodynamics in the NaBH4+LaF3 composite.
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