Abstract

Abstract Scaling up stirred tanks is a significant challenge because of the research gaps between laboratory and industrial-scale setups. It is necessary to understand the effects of scale-up on the mass transfer in stirred tanks, and this requires meticulous experimental analysis. The present study investigates the effects of tank size and aspect ratio ( H L T $\sfrac{{H}_{L}}{T}$ ) on the volumetric mass transfer coefficients of shear-thinning fluids. The experiments were conducted in three stirred tanks of different sizes (laboratory and pilot scale) and geometries (standard and nonstandard). H L T $\sfrac{{H}_{L}}{T}$ was 1 for the standard tanks and 3.5 for the nonstandard stirred tanks. Three sizes of stirred tanks were used: 11 L with H L T $\sfrac{{H}_{L}}{T}$ of 1, 40 L with H L T $\sfrac{{H}_{L}}{T}$ of 3.5, and 47 L with H L T $\sfrac{{H}_{L}}{T}$ of 1. Impeller stirring speeds and gas flow rates were in the range of 800–900 rev min−1 and 8–10 L min−1, respectively. The volumetric mass transfer coefficient was estimated based on the dissolved oxygen concentration in the fluids, and the effects of rheology and operating conditions on the volumetric mass transfer coefficient were observed. The volumetric mass transfer coefficient decreased as tank size increased and increased with an increase in operating conditions, but these effects were also clearly influenced by fluid rheology. The impacts of scale-up and operating conditions on the volumetric mass transfer coefficient decreased as liquid viscosity increased.

Highlights

  • Scaling up stirred tanks in the presence of non-Newtonian fluids is highly challenging because of difficulties in translating the mass transfer process from the laboratory to the industrial scale

  • The present study investigates the effects of tank size and aspect ratio (HL/T) on the volumetric mass transfer coefficients of shear-thinning fluids

  • The volumetric mass transfer coefficient was estimated based on the dissolved oxygen concentration in the fluids, and the effects of rheology and operating conditions on the volumetric mass transfer coefficient were observed

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Summary

Introduction

Scaling up stirred tanks in the presence of non-Newtonian fluids is highly challenging because of difficulties in translating the mass transfer process from the laboratory to the industrial scale. The time response (τp) of O2 sensors poses a problem with dynamic methods (Bandyopadhyay, Humphrey, and Taguchi 1967) when the τp is higher than the characteristic time of mass transfer (1/kLa) Another concern about applying the dynamic method to viscous non-Newtonian fluids is the appearance of tiny gas bubbles suspended in such liquids. The contribution of these microbubbles to kLa is significantly smaller than that of large bubbles owing to low driving force (Muller and Davidson 1992; Shetty, Kantak, and Kelkar 1992). Microbubbles are considered perfectly mixed, and their effect on kLa is mostly

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