Abstract
In this paper, we investigate the phase transition of Reissner-Nordstr\om-AdS (RN-AdS) black holes in ($3+1$)-dimensional Gauss-Bonnet gravity in the extended thermodynamic phase space. Since the Gauss-Bonnet term is a topological invariant, it does not contribute to the spacetime, the global charges and their conjugate potentials, the equation of state, and the critical phenomena macroscopically or the coexistence states, coexistence curves, and molecule number densities microscopically. However, the entropy, the first law of thermodynamics, and Smarr relation are modified owing to the Gauss-Bonnet term. Also, in contrast to the case in Einstein gravity, the Hawking-Page phase transition happens at a different temperature induced by the modified entropy. Especially, the positivity of the entropy results in a constraint on the special volume, which does bring the RN-AdS black hole to the reentrant phase transition and changes the whole phase structure. The temperatures of the zero and first order phase transition are analytically given. The phase structure is dependent on the electric charge $Q$ and Gauss-Bonnet coupling $\ensuremath{\alpha}$, while in the reduced parameter space, it depends only on the dimensionless special volume of zero entropy state ${\ensuremath{\nu}}_{S}=\frac{\sqrt{2|\ensuremath{\alpha}|}}{\sqrt{3}Q}$, rather than $Q$ and $\ensuremath{\alpha}$. Moreover, this is the first analytical example in which the structure of the reentrant phase transition and the effect of the entropy constraint are presented.
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