Effects of Flue Gas Impurities on the Performance of Rare Earth Denitration Catalysts

Abstract

Selective catalytic reduction (SCR) is still the most widely used process for controlling NOx gas pollution. Specifically, commercial vanadium-based catalysts have problems such as narrow operating temperature range and environmental pollution. Researchers have developed a series of cerium-based catalysts with good oxygen storage performance and excellent redox performance of CeO2. However, the anti-poisoning performance of the catalyst is the key to its application. There are many kinds of impurities in the flue gas, which has a huge impact on the catalyst. The deposition of substances, the reduction of active sites, the reduction of specific surface area, and the reduction of chemically adsorbed oxygen will affect the denitration activity of the catalyst to varying degrees, and the poisoning mechanism of different impurities on the catalyst is also different. Therefore, this review divides the impurities contained in flue gas into different types such as alkali metals, alkaline earth metals, heavy metals, and non-metals, and summarizes the effects and deactivation mechanisms of various types of impurities on the activity of rare earth catalysts. Finally, we hope that this work can provide a valuable reference for the development and application of NH3-SCR catalysts for rare earth denitration in the field of NOx control.