Effects of external magnetic field and hydrostatic pressure on magnetic and structural phase transitions in Pr0.6Sr0.4MnO3

Abstract

We investigate the effect of hydrostatic pressure on the temperature dependence of magnetization and also the influence of magnetic field on the linear thermal expansion in polycrystalline Pr0.6Sr0.4MnO3, which is ferromagnetic at room temperature (TC = 305 K) but its magnetization undergoes an abrupt decrease at TS = 89 K within the ferromagnetic state. Normal and inverse magnetocaloric effects around TC and TS, respectively, were reported earlier in this single phase compound [Repaka et al., J. Appl. Phys. 112, 123915 (2012)]. The thermal expansion shows an abrupt decrease at TS in zero magnetic field but transforms into an abrupt increase at the same temperature under 7 T, which we interpret as a consequence of magnetic field-induced structural transition from the low-temperature monoclinic (I2/a symmetry) to high-temperature orthorhombic (Pnma symmetry) phase in corroboration with a published neutron diffraction study in zero magnetic field. While the external magnetic field does not change TS, the application of a hydrostatic pressure of P = 1.16 GPa shifts the magnetic anomaly at TS towards high temperature. The pressure induced shift of the low-temperature magneto-structural anomaly (ΔTS = 27 K) is nine-times higher than that of the ferromagnetic Curie temperature (ΔTC = 3 K). Our results suggest that while the hydrostatic pressure stabilizes the low temperature monoclinic phase at the expense of the orthorhombic phase, the applied magnetic field does not affect the structural transition temperature.