Abstract

Effects of excess ZnO addition on phase structure, dielectric and piezoelectric properties in La-doped Lead zinc niobate, Pb(Zn 1/3Nb 2/3)O 3 (PZN)–PZT systems have been investigated. Addition of excess ZnO helps to suppress the formation of the pyrochlore phase. Microstructure revealed the grains size to decrease with excess ZnO addition. Enhanced T max and d 33, and reduced ɛ max and Tan δ were observed. Adding proper excess ZnO in La-like doped PZN-based systems seems an effective approach to suppress the formation of the pyrochlore phase, enhance piezoelectric constant d 33 and reduce dielectric loss.

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