Effects of Elements on the Microstructure and Mechanical Properties of AlCoCrFeNiTi High-Entropy Alloys

Abstract

AlCoCrFeNiTi high-entropy alloys (HEAs) have attracted much attention because of their excellent mechanical properties. Here, we systemically studied the effects of elements on the microstructure and mechanical properties of AlCoCrFeNiTi HEAs. The results showed that the phase composition and morphology are significantly affected by the elements. With increasing Ti addition, the lattice parameters of the solid solution phase increased slightly, and lattice distortion occurred. Al changes the crystal structure of FCC to BCC and reduces the lattice distortion energy of the alloy. The BCC phase obviously increases with increasing Al content. However, excessive Al, Ti and Cr promote the formation of intermetallic compound phases, while Ni, Fe and Co promote the transformation of the alloy into a solid solution. The properties of AlCoCrFeNiTi HEAs are closely related to their phase composition and morphology. When HEAs consist only of FCC and BCC phases, their ductility and strength are greatly improved. The presence of an intermetallic compound phase in the microstructure can significantly reduce the configurational entropy of adjacent solid solutions, thus reducing the strengthening effect of solid solutions. Additionally, the AlCoCrFeNiTi HEAs with different microstructures show different deformation mechanisms. The deformation of FCC + BCC HEAs with cellular structures is uniform and presents great plasticity and strength. When the cellular-structure HEAs contain equiaxed BCC, thick lamellar BCC/FCC or intermetallic compound phases, cracks tend to occur and propagate along the phase boundary due to the local nonuniform deformation. For AlCoCrFeNiTi HEAs with dendrite structures, after initiation at the phase boundary, the crack does not easily spread to the dendrite FCC phase but causes the interdendritic BCC phase to crack.