Abstract
The "dipolar" spin-lattice relaxation time in aluminum has been measured for temperatures between $1.3\ifmmode^\circ\else\textdegree\fi{}\mathrm{K}<T<295\ifmmode^\circ\else\textdegree\fi{}\mathrm{K}$. In contrast to the Zeeman spin-lattice relaxation time ${T}_{1z}$, the dipolar time does not vary linearly with $\frac{1}{T}$. This is interpreted in terms of cross relaxation between different groups of nuclear spins, some of which experience quadrupole interactions as a result of defects in the lattice, and others which are well removed from such defects. Both cross-relaxation and spin-lattice effects have been measured by our technique; a three-bath model of the nuclear-spin system permits a separation of these effects, with a true dipolar relaxation time ${T}_{1dd}$ related to ${T}_{1z}$ by $\ensuremath{\delta}=\frac{{T}_{1z}}{{T}_{1dd}}=2.15\ifmmode\pm\else\textpm\fi{}0.07$, $\ensuremath{\delta}$ being independent of temperature. This enhancement of $\ensuremath{\delta}$ over the value 2.00 and the enhancement of the Korringa relation between ${T}_{1z}$ and $K$, the Knight shift, are discussed and compared with the predictions of the theory of Wolff in which the effects of electron-electron interactions are considered. A similar analysis in sodium is included for comparison, sodium being the metal to which the theory is best applicable.
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