Abstract
Perovskite-type Ca1−2xDyxYbxMnO3 (0≤x≤0.10) ceramics were synthesized by solid state reaction. Microstructures were characterized and thermoelectric properties were evaluated between 300K and 1100K. The samples obtained in this work have high relative densities with compact grains. The electrical resistivity shows a typical metallic conductivity behavior, and decreases with substitution. The Seebeck coefficients are negative, indicating n-type conduction, and the largest value is obtained −181μV/K at x=0.02. The highest power factor 415μW/(K2m) and the highest figure of merit 0.27 are both obtained for x=0.02 sample, and the ZT is about five times as much as un-doped CaMnO3 sample.
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