Effects of driving conditions on aerosol formation from photooxidation of gasoline vehicles exhaust in Hong Kong

Abstract

The emissions before and after atmospheric oxidation from three gasoline vehicles were characterized under different driving conditions (idling, cruising and New European Driving Cycle (NEDC)). The total quantified volatile organic compounds (VOCs) emission factors for the vehicles ranged from 18.4 to 2728.7 mg/kg depending on driving conditions. The organic aerosol mass concentrations showed substantial increase (∼7.6–10.8 times) after ageing process, implying that vehicular emissions were an important source of secondary organic aerosols (SOAs). The total quantified organic aerosol mass concentrations in aged samples ranged from 77.7 to 480.5 ng m−3 under different test conditions. Aromatic and alkenoic acids were identified as major organic aerosols after ageing. The emission factors of VOCs were higher under idling condition compared to the other driving modes for all vehicles. High VOCs emissions can potentially lead to high secondary organic aerosol (SOA) formation inside the reactor and more robust SOA formation under idling condition in all analysis. The gasoline direct injection (GDI) vehicle with latest year of manufacture in EURO 4 standard can pose lower primary emissions of organic substances, but nevertheless the composition of emitted VOCs demonstrates higher SOA yield and SOA formation. Further analysis proposes engine type is the key factor on primary VOC composition under idling. The findings suggest a need to revise existing regulation of composition of organic substances.